Title of article :
A structurally characterised ruthenium bis(pyrazolyl)borate benzylidene complex containing an agostic Ru⋯H–C interaction: synthesis and catalytic activity
Author/Authors :
Jim Patel، نويسنده , , W.Roy Jackson، نويسنده , , Algirdas K. Serelis، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Abstract :
A ruthenium bis(pyrazolyl)borate benzylidene has been synthesised. A single crystal X-ray diffraction study showed that the complex contained an agostic Ru⋯H–C interaction. The complex displayed catalytic activity for the ring closing metathesis of diethyl diallylmalonate in the presence of CuCl as a co-catalyst in refluxing toluene.
Keywords :
Ruthenium , Olefin metathesis
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA