Title of article
Rhodium(I) complexes with phosphinooxathiane (POT) and phophinooxazolidine (POZ) ligands: the crystal structures of [(POT)Rh(CO)Cl] and [(POZ)Rh(CO)Cl]
Author/Authors
Gustavo R??os-Moreno، نويسنده , , Rubén A. Toscano، نويسنده , , Roc?o Red?n، نويسنده , , Hiroto Nakano، نويسنده , , Yuko Okuyama، نويسنده , , David Morales-Morales*، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
7
From page
303
To page
309
Abstract
The reactions of two equivalents of the ligands POT or POZ with one equivalent of the rhodium complex [Rh(μ-Cl)(CO)2]2 afford the complexes [(POT)Rh(CO)Cl] (1) and [(POZ)Rh(CO)Cl] (2), respectively. The crystal structures of both complexes have been determined showing the rhodium centers to be into slightly distorted square planar environments. Preliminary screening of the catalytic systems POT/Rh and POZ/Rh in the asymmetric hydroformylation of styrene has been carried out.
Keywords
crystal structures , Catalysis , Phosphorus–sulfur ligands , Phosphorus–nitrogen ligands , Rhodium complexes , Asymmetric hydroformylation
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2005
Journal title
INORGANICA CHIMICA ACTA
Record number
1322523
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