Title of article
Cyclopentadienyl ruthenium(II) dithiocarbamate complexes: Crystal structures of [CpRu(PPh3)(S2CNPr2)] and [CpRu(PPh3)(S2CNMeBu)]
Author/Authors
Graeme Hogarth، نويسنده , , Simon Faulkner، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
1018
To page
1022
Abstract
Thermolysis of [CpRuCl(PPh3)2] and NaS2CNPr2 or NaS2CNMeBu in methanol affords the ruthenium(II) dithiocarbamate complexes, [CpRu(PPh3)(S2CNPr2)] and [CpRu(PPh3)(S2CNMeBu)], which have been crystallographically characterized. A similar treatment of two equivalents of [CpRuCl(PPh3)2] with the bis(dithiocarbamate) ligand derived from 1,3-homopiperazine affords [{CpRu(PPh3)}2(μ-S2CNC5H10NCS2)].
Keywords
Cyclopentadienyl , Homopiperazine , Dithiocarbamate , Ruthenium , Phosphine
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1323374
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