Title of article
Arylation of non-activated C–Cl bond with Grignard reagents catalyzed by pincer [PCP]-nickel complexes
Author/Authors
Sun، نويسنده , , Yunqiang and Li، نويسنده , , Xiaoyan and Sun، نويسنده , , Hongjian، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
3
From page
95
To page
97
Abstract
A series of pincer Ni(II) complexes were prepared and utilized in the cross-coupling reaction of non-activated aryl chlorides with Grignard reagents (The Kumada reaction). Catalytic studies revealed that complex 5 ([Ph-PNCNP-Ph]-Ni-Cl) showed the highest catalytic activity for the cross-coupling reaction in the presence of 2 mol% catalyst under mild reaction condition.
Keywords
Pincer Ni(II) complexes , Kumada cross-coupling reaction , Non-activated C–Cl bond
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2014
Journal title
INORGANICA CHIMICA ACTA
Record number
1323826
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