Title of article
A convenient synthesis of bis(phosphino)methanes: Formation of a nickel(II) bis(phosphino)methane monoxide complex
Author/Authors
Juan C?mpora، نويسنده , , Celia M. Maya، نويسنده , , Inmaculada Matas، نويسنده , , Birgit Claasen، نويسنده , , Pilar Palma، نويسنده , , Eleuterio Alvarez، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
3191
To page
3196
Abstract
The reaction of (trimethylsilyl)methyl phosphines R2PCH2SiMe3 with chlorophosphines View the MathML sourceClPR2′ provides ready access to a range of symmetrical or non-symmetrical diphosphinomethanes View the MathML sourceR2PCH2PR2′. The products are obtained cleanly and can be used directly in the synthesis of transition metal complexes. This is illustrated by the preparation and structural characterization of the corresponding NiCl2(P–P) derivatives.
Keywords
Diphosphine ligands , Diphosphine monoxide , nickel
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324103
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