Title of article
Synthesis, structure, and photophysical properties of a bis-cyclometalated heteroleptic iridium(III) complex containing 2,2′-dipyridylamine
Author/Authors
Mei Ching Tseng، نويسنده , , Wei Lin Su، نويسنده , , Yu Cheng Yu، نويسنده , , Shao Pin Wang، نويسنده , , Wen Liang Huang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
4144
To page
4148
Abstract
The synthesis, X-ray crystal structure and luminescence properties of a new bis-cyclometalated heteroleptic complex, [Ir(ppy)2(HDPA)](PF6) (1, ppy = 2-phenylpyridine, HDPA = 2,2′-dipyridylamine), are reported. Both at room temperature and 77 K, complex 1 exhibits intense blue emission, assigned as 3MLCT [dπ(Ir)–π∗(HDPA)] phosphorescence. Analysis of voltammetric data also provides evidence in support of this assignment.
Keywords
Iridium(III) , Cyclometalated complex , Phosphorescence
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324227
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