Title of article
Hydrogen bonding interaction between imidazolyl N–H group and peroxide: Stabilization of Mn(III)-peroxo complex TpiPr2Mn(η2-O2)(imMeH) (imMeH = 2-methylimidazole)
Author/Authors
Udai P. Singh، نويسنده , , Asish K. Sharma، نويسنده , , Shiro Hikichi*، نويسنده , , Hidehito Komatsuzaki، نويسنده , , Yoshihiko Moro-Oka، نويسنده , , Munetaka Akita، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
5
From page
4407
To page
4411
Abstract
A mononuclear side-on peroxo managanese (III) complex, TpiPr2Mn(η2-O2)(imMeH) (3) was prepared by the reaction of [TpiPr2Mn(O)]2 with excess amount of H2O2 in the presence of 2-methylimidazole (imMeH). Its X-ray structure clearly demonstrated the involvement of intermolecular hydrogen bonding interaction between η2-peroxide and imidazolyl N–H functional group. Complex 3 was stable, green in color and unable to oxygenate triphenylphosphine and ethyl vinyl ether.
Keywords
2-Methylimidazole , Manganese(III) , Peroxo complex , crystal structure
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2006
Journal title
INORGANICA CHIMICA ACTA
Record number
1324261
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