Title of article :
Reactions of Re(III) with α-diketones: Oxidative addition
Author/Authors :
M.N. Sokolov، نويسنده , , N.E. Fyodorova، نويسنده , , R. Paetow، نويسنده , , Christiane D. Fenske، نويسنده , , A.G. Ravelo، نويسنده , , A.Yu. Naumov، نويسنده , , V.E. Fedorov، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2007
Abstract :
The reactions of [ReCl3(CH3CN)(PPh3)2] with benzil PhC(O)C(O)Ph, and with a natural 1,2-naphthoquinone derivative, β-lapachone (Lap), result in oxidative addition with the formation of Re(V) complexes with stilbenediolate, [ReCl3(PhC(O)double bond; length as m-dashC(O)Ph)(PPh3)] (1) and with a reduced semiquinonic form of lapachone, [ReIVCl3(Lap−)(PPh3)] (2). The structures of both compounds were established by X-ray crystallography.
Keywords :
Benzil , Charge delocalization , ?-Lapachone , crystal structures , Rhenium
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
