Title of article :
Synthesis, spectroscopy, computational evaluation and first X-ray structural characterization of a primary amine containing boronium ion
Author/Authors :
Morgan D. Soutullo، نويسنده , , Carl I. Odom، نويسنده , , Ashley B. Smith، نويسنده , , De’Arco R. McCreary، نويسنده , , Richard E. Sykora، نويسنده , , E. Alan Salter، نويسنده , , Andrzej Wierzbicki، نويسنده , , James H. Davis Jr.، نويسنده ,
Abstract :
Stable (CF3SO2)2N−, I− and View the MathML sourceBPh4- salts of the boronium ion [(tert -butylamine)(1-methylimidazole)BH2]+ have been isolated and characterized. A single-crystal X-ray structure of the View the MathML sourceBPh4- salt provides the first unambiguous proof for a boronium ion supported by a primary amine ligand.
Keywords :
Computational studies , X-ray crystal structures , Boronium ions , boron compounds , Synthesis
