Author/Authors :
J.C. Dias، نويسنده , , A. Soriano-Portillo، نويسنده , , M. Clemente-Léon، نويسنده , , C. Giménez-Saiz، نويسنده , , J.R. Gal?n-Mascar?s، نويسنده , , C.J. G?mez-Garc?´a، نويسنده , , Boris E. Coronado MD، نويسنده ,
Abstract :
Salts of the Fe(III) spin crossover cation [FeIII(qsal)2]+ (qsalH = N-(8-quinolyl)salicylaldimine) and monoanions [MIII(pds)2]− (M = Cu, Au; pds = pirazine-2,3-diselenolate) with formula [FeIII(qsal)2][MIII(pds)2] were prepared and characterized by single crystal X-ray diffraction and magnetic measurements. These two salts present magnetic properties essentially due to the FeIII centres in the high-spin state (S = 5/2), and do not have any spin transition.
