Author/Authors :
Scheidt، نويسنده , , W. Robert and Buentello، نويسنده , , Kristin E. and Ehlinger، نويسنده , , Noelle and Cinquantini، نويسنده , , Arnaldo and Fontani، نويسنده , , Marco and Laschi، نويسنده , , Franco، نويسنده ,
Abstract :
The electrochemistry of [Cu(OEP)] and [Ni(OEP)] are compared with the mixed-valence π-cations [ Cu ( OEP ) / 2 ] 2 + and [ Ni ( OEP ) / 2 ] 2 + . These electrochemical studies, carried out with cyclic voltammetry and hydrodynamic voltammetry, show that the mixed valence π-cations have distinct electrochemical properties, although the differences between the [M(OEP)]+/0 and [ M ( OEP ) / 2 ] 2 + / 0 processes are subtle.
Keywords :
Metalloporphyrins , mixed valence , Electrochemistry , ?-Cation radicals
