Title of article :
Expanding the 4,4′-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine, M = Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer
Author/Authors :
Jonathon E. Beves، نويسنده , , Jonathon E. and Bray، نويسنده , , David J. and Clegg، نويسنده , , Jack K. and Constable، نويسنده , , Edwin C. and Housecroft، نويسنده , , Catherine E. and Jolliffe، نويسنده , , Katrina A. and Kepert، نويسنده , , Cameron J. and Lindoy، نويسنده , , Leonard F. and Neuburger، نويسنده , , Markus and Price، نويسنده , , David J. and Schaffner، نويسنده , , Silvia and Schape، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The solid state structures of [Ni(1)2][NO3]2 · 2MeOH · 2H2O, [Fe(1)2][ClO4]2 · 2MeOH · 0.5H2O, [Ru(1)2][PF6]2 and [Ru(1)2][PF6][NO3] (1 = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine) are presented and the structural variation observed for the {M(1)2}2+ unit is discussed. Protonation of the pendant pyridine group in [Ru(1)2]2+ leads to the formation of a hydrogen-bonded, one-dimensional polymer [{Ru(1)(H1)}n]3n+ exemplifed by the solid-state structure of [{Ru(1)(H1)}{Fe(NCS)6} · 1.25H2O]n.
Keywords :
2 , 2?:6? , 2?-Terpyridine , Iron(II) , Nickel(II) , Ruthenium(II) , Coordination polymer , Crystallography
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
