Title of article :
Bond cleavage reactions in substituted thiophenes by a rhodium complex
Author/Authors :
Myers، نويسنده , , Andrew W. and Dong، نويسنده , , Lingzhen and Ate?in، نويسنده , , Tülay A. and Skugrud، نويسنده , , Roger and Flaschenriem، نويسنده , , Christine and Jones، نويسنده , , William D.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
The reactions of (C5Me5)Rh(PMe3)(Ph)H with 2-methoxythiophene, 3-methoxythiophene, 2-cyanothiophene, 3-cyanothiophene, 2-trimethylsilylthiophene, ethylenesulfide, trimethylenesulfide, and several polymethylthiophenes have been investigated. These thiophene derivatives give C–S and in one case C–H insertion products. Ethylene sulfide and trimethylene sulfide undergo ring opening or desulfurization.
Keywords :
Hydrodesulfurization , C–S activation , C–H activation
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
