Title of article
Lanthanide-induced hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid esters
Author/Authors
Tanja Steinkamp، نويسنده , , Heiko Hayen، نويسنده , , Jurriaan Huskens، نويسنده , , Uwe Karst، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
421
To page
425
Abstract
The hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid (DPPDA) esters is induced by lanthanide(III) ions. As the related 2,6-pyridinedicarboxylic acid esters are not cleaved, the effect is traced back on improved complexation of the lanthanides by the DPPDA esters. Time-resolved fluorescence spectroscopic and electrospray mass spectrometric investigations on the esters provide information on the progress of the reactions.
Keywords
Catalysis , Luminescence , Electrospray mass spectrometry , Phenanthroline , Lanthanide complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1326659
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