Title of article
trans-[RuIII(N-N)2Cl2]+ species, where N-N is bis(3,5-dimethylpyrazol-1-yl)methane
Author/Authors
Michael G.B. Drew، نويسنده , , Samik Nag، نويسنده , , Dipankar Datta، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
591
To page
594
Abstract
Using bis(3,5-dimethylpyrazol-1-yl)methane as an N-N donor ligand, a trans-[RuIII(N-N)2Cl2]+ core has been isolated from the direct reaction of the ligand with RuCl3 · xH2O and characterized structurally for the first time. The core displays a rhombic EPR spectrum and a quasireversible Ru(II/III) couple with an E1/2 of −0.34 V versus NHE.
Keywords
EPR , crystal structure , Ruthenium , DFT , Pyrazole
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1326685
Link To Document