Title of article
A structural investigation of the heterobimetallic carbocation complex [Cp∗(CO)2Fe{μ-CH2CH(CH2)3}W(CO)3Cp]BPh4
Author/Authors
Evans O. Changamu، نويسنده , , Holger B. Friedrich، نويسنده , , Manuel A. Fernandes، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
2947
To page
2950
Abstract
The reaction of [Cp∗(CO)2Fe{μ-CH2CH(CH2)3}W(CO)3Cp]PF6 with NaBPh4 in dry acetone gave [Cp∗(CO)2Fe{μ-CH2CH(CH2)3}W(CO)3Cp]BPh4. The bond Fe–Cβ is shorter than that reported for the shorter chain carbocationic complexes. The data suggest that metallacyclopropane character is on the iron side of the molecule both in the solid state and in solution.
Keywords
Carbocationic complex , Metallacyclopropane , Heterobimetallic , Iron , Tungsten
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1327617
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