Title of article
Crystal structure, neutron vibrational spectroscopy, and DFT calculations of Li2B12H12 · 4H2O
Author/Authors
Muhammed Yousufuddin، نويسنده , , Jae-Hyuk Her، نويسنده , , Wei Zhou، نويسنده , , Satish S. Jalisatgi، نويسنده , , Terrence J. Udovic، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
3155
To page
3158
Abstract
The crystal structure of Li2B12H12 · 4H2O has been determined by X-ray powder diffraction and confirmed by a combination of neutron vibrational spectroscopy and first-principles calculations. The solvent-free analog of this compound (Li2B12H12) has recently attracted interest as a putative intermediate in the decomposition of LiBH4. Li2B12H12 · 4H2O appears in the initial stages of Li2B12H12 synthesis from LiBH4 and B10H14
Keywords
crystal structure , lithium borohydride , Neutron scattering , Neutron spectroscopy , Metal hydride , Tetrahydrate , X-ray diffraction , Dodeca-hydrododecaborate , Vibrational spectroscopy
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1327648
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