Title of article
Synthesis and structural characterisation of the phenyl/scorpionate hybrid ligand [Ph(pz)BC5H10]−
Author/Authors
Kerstin Kunz، نويسنده , , Florian Blasberg، نويسنده , , Michael Bolte، نويسنده , , Hans-Wolfram Lerner، نويسنده , , Matthias Wagner، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
5
From page
4372
To page
4376
Abstract
The new phenyl/scorpionate hybrid ligand [Ph(pz)BC5H10]− has been synthesised and structurally characterised as K+ and Tl+ salt. The ligand is specifically designed to create half-sandwich complexes in which the metal ion is chelated by the π-electron system of the phenyl ring and by the electron lone pair of the pyrazolyl nitrogen atom. This structural motif is established both by K[Ph(pz)BC5H10] and by Tl[Ph(pz)BC5H10].
Keywords
Arene ligands , Boron , Ligand design , N-ligands
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1327827
Link To Document