Title of article :
High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands
Author/Authors :
Ivan Nemec، نويسنده , , Roman Bo?a، نويسنده , , Milan Gembick?، نويسنده , , Lubor Dlhan، نويسنده , , Radovan Herchel، نويسنده , , Franz Renz، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Abstract :
Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mössbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.
Keywords :
Iron(III) complex , structure , M?ssbauer spectroscopy , Magnetism , N-oxide ligands , Schiff-base ligands
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
