Title of article
Synthesis and characterization of Fe(III)(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2)
Author/Authors
Jo?o C. Dias، نويسنده , , Bruno Vieira، نويسنده , , Isabel C. Santos، نويسنده , , Laura C.J. Pereira، نويسنده , , Vasco da Gama، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
2076
To page
2079
Abstract
Compounds FeIII(3-CH3O-qsal)2PF6 · nH2O (n = 0, 2) (1, 1 · 2H2O) were synthesized and characterized: the structure of 1 and the magnetic properties of both compounds were determined. Compound 1 · 2H2O presents properties characteristic of high-spin Fe(III), while 1 presents properties of low-spin Fe(III) with an onset of a gradual spin crossover at ca. 300 K.
Keywords
Spin crossover , Magnetic properties , Ligands , crystal structures , Iron(III)
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2009
Journal title
INORGANICA CHIMICA ACTA
Record number
1328178
Link To Document