Title of article
Investigation of the solution behavior of tri-n-butylphosphine copper(I) and silver(I) acetates using 31P{1H} NMR spectroscopy
Author/Authors
Siegert، نويسنده , , Uwe and Hahn، نويسنده , , Harald and Lang، نويسنده , , Heinrich، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
944
To page
948
Abstract
31P{1H} NMR spectra of metal–organic [(nBu3P)mMO2CMe] (M = Cu, Ag; m = 1, 1.5, 2, 2.5, 3, 3.5, 4) have been studied in the temperature range of 308–178 K. Exchange parameters were determined for the appropriate silver(I) complexes. Possible ligand exchange mechanisms based on dissociative and associative processes are discussed.
Keywords
Exchange parameters , Copper(I) , silver(I) , Acetate , NMR spectroscopy
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2010
Journal title
INORGANICA CHIMICA ACTA
Record number
1328288
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