• Title of article

    Halo-complexes of titanium(III): The thermochromic behaviour of [NBu4][TiCl4(THF)2]

  • Author/Authors

    Biagini، نويسنده , , Paolo and Bonoldi، نويسنده , , Lucia and Marchetti، نويسنده , , Fabio and Pampaloni، نويسنده , , Guido، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2010
  • Pages
    3
  • From page
    3637
  • To page
    3639
  • Abstract
    TiCl3(thf)3 reacts with ACl (A = NBu4, PPN; PPN = Ph3PNPPh3) in dichloromethane solution, affording the compounds A[TiCl4(thf)2] (A = NBu4, 1; A = PPN, 2). Compound 1, dissolved in CH2Cl2, exhibits thermochromic behaviour which has been the subject of variable-temperature UV–Vis investigations.
  • Keywords
    UV–VIS , chloride , Thermochromism , ion pairs , Titanium(III)
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2010
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1328665