Title of article :
Synthesis and characterization of β-diketiminate germanium(II) and tin(II) bromides
Author/Authors :
Jana، نويسنده , , Anukul and Schwab، نويسنده , , Gerald and Roesky، نويسنده , , Herbert W. and Stalke، نويسنده , , Dietmar، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
The equimolar reaction of a β-diketiminate lithium salt LLi(OEt2) [L = HC(CMeNAr)2; Ar = 2,6-iPr2C6H3] with either GeBr2 or SnBr2 in diethyl ether affords the synthetically useful monomeric β-diketiminate-element halides LGeBr (1) and LSnBr (2), respectively. Both are soluble in hydrocarbon solvents, stable in inert atmosphere, and have been characterized by elemental analysis, NMR spectroscopy, and single-crystal X-ray diffraction analysis.
Keywords :
Bromide , TIN , X-Ray , ?-Diketiminate , Germanium
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
