Title of article :
Layered (2-D) structure of [Ru2(O2CMe)4]2[Ni(CN)4] determined via Rietveld refinement of synchrotron powder diffraction data
Author/Authors :
Her، نويسنده , , Jae-Hyuk and Stephens، نويسنده , , Peter W. and Kennon، نويسنده , , Bretni S. and Liu، نويسنده , , Chen and Miller، نويسنده , , Joel S.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
Reaction of [Ru2(O2CMe)4]Cl and K2[Ni(CN)4] forms [Ru2(O2CMe)4]2[Ni(CN)4] with the targeted layered structure possessing Ru–NCNi linkages, albeit strained, with Ru–NC and Ni–CN angles in the range of 147–167°. The magnetic properties of [Ru2(O2CMe)4]2[Ni(CN)4] can be fit to a zero-field splitting model with D/kB = 95 K (66 cm−1).
Keywords :
Layer structure , Ruthenium acetate , Rietveld refinement , Nickel complex , X-ray structures
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
