Title of article
Cyclopalladation of N-phenylbenzamides: Synthesis and structure of bimetallic palladium(II)-complexes
Author/Authors
Borduas، نويسنده , , Nadine and Lough، نويسنده , , Alan J. and Dong، نويسنده , , Vy M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
6
From page
247
To page
252
Abstract
Three bimetallic palladium(II) complexes were generated by cyclopalladation of N-methyl-N-phenylbenzamide derivatives, substrates known to undergo oxidative intramolecular cross-coupling via palladium catalysis. These isolable Pd-complexes were characterized by X-ray crystallography. Stoichiometric and catalytic experiments with [(3-methoxy-N-methyl-N-phenylbenzamide)Pd(μ-TFA)]2 were investigated, and this palladium complex was found to be an effective precatalyst for oxidative cross-coupling.
Keywords
Intramolecular reaction , C–H activation , Oxidative cross-coupling , Palladium(II) dimer
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2011
Journal title
INORGANICA CHIMICA ACTA
Record number
1329600
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