Author/Authors :
Chiozzone، نويسنده , ,
Raul M. Gonzalez، نويسنده , , Ricardo and Kremer، نويسنده , , Carlos and Armentano، نويسنده , , Donatella and De Munno، نويسنده , , Giovanni and Julve، نويسنده , , Miguel and Lloret، نويسنده , , Francesc، نويسنده ,
Abstract :
A novel oxalato-bridged rhenium(IV)-copper(II) compound, namely [ReIVBr4(μ-ox)CuII(bpy)2] (1), has been obtained by reacting (PPh4)2[ReBr4(ox)] with Cu(CF3SO3)2 and 2,2′-bpy in CH3CN, and its crystal structure determined by single-crystal X-ray diffraction. Intermolecular Br⋯Br interactions and nonbonding Cu⋯Br type contacts between the heterobimetallic dinuclear units lead to a two-dimensional supramolecular structure. Compound 1 behaves magnetically as a [ReIVCuII]2 tetranuclear species with weak antiferromagnetic interactions through the oxalato bridge and intermolecular Br⋯Br contacts.
Keywords :
Rhenium(IV) complexes , crystal structure , Magnetic properties , Oxalato complexes
