Title of article :
Coordination chemistry of the heterotopic 1,2-phenylenebis(thio)diacetic acid ligand: Rhodium(I), palladium(II) and nickel(II) complexes
Author/Authors :
R. Berghof، نويسنده , , Christiane and Grosu، نويسنده , , Ioana Georgeta and L?nnecke، نويسنده , , Peter and G?mez-Ruiz، نويسنده , , Santiago and Silaghi-Dumitrescu، نويسنده , , Luminita and Hey-Hawkins، نويسنده , , Evamarie، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
Starting from the heterotopic multidentate ligand 1,2-phenylenebis(thio)diacetic acid (1), cis-rac-[PdCl2{1,2-(HOOCCH2S)2C6H4-κ2S,S′}] (2), cis-rac-[Rh{1,2-(HOOCCH2S)2C6H4-κ2S,S′}(cod)]BF4 (3) and cis-rac-[Ni{1,2-(OOCCH2S)2C6H4-κ4O,O′S,S′}{cis-(C3H4N2)}2] (4) were prepared and characterised by X-ray diffraction and conventional spectroscopic techniques. Compounds 1–4 show extensive hydrogen-bonded networks (XH⋯O, X = O, N) in the solid state.
Keywords :
1 , Rhodium complex , Nickel complex , Palladium complex , X-ray crystal structure , Hydrogen bonding , 2-Phenylenebis(thio)diacetic acid
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
