Title of article :
Dinuclear iridium complexes with unsupported Ir–Cl–Ir bridges
Author/Authors :
Merola، نويسنده , , Joseph S. and Husebo، نويسنده , , Trang Le and Selnau، نويسنده , , Henry E.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
Two unusual dinuclear iridium complexes are reported with unsupported bridging chloride ligands. The first comes from an aqueous solution of H2ClIr(PMe3)3 by the addition of KPF6.
cond is formed in the reaction between H(C6H5)ClIr(PMe3)3 and TlPF6 in dichloromethane.
crystal X-ray structures are provided for both μ-chlorodiiridium complexes.
Keywords :
X-ray structures , Iridium compounds , Bridging chloride
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
