Title of article
Preparation and characterization of N,N-diacetatodithiocarbamato metal complexes with large negative charges
Author/Authors
Vanthoeun، نويسنده , , Keo and Bunho، نويسنده , , Toh and Mitsuhashi، نويسنده , , Ryoji and Suzuki، نويسنده , , Takayoshi and Kita، نويسنده , , Masakazu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
410
To page
414
Abstract
New metal complexes with N,N-diacetatodithiocarbamate (Ac2dtc3−), Na6[Co(Ac2dtc)3], Ba3[Co(Ac2dtc)3], Na4[Ni(Ac2dtc)2], Ba2[Ni(Ac2dtc)2], Na4[Cu(Ac2dtc)2] and Ba2[Cu(Ac2dtc)2], have been synthesized, and their molecular structures and spectroscopic properties have been characterized. The X-ray analysis of Ba3[Co(Ac2dtc)3]·16H2O confirmed a well-organized and rigid network among carboxyl groups of the complex anions, barium cations, and water molecules.
Keywords
Dithiocarbamato complex , Large negative charge , crystal structure , Network Structure
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2013
Journal title
INORGANICA CHIMICA ACTA
Record number
1331457
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