Title of article
Platinum(II) complexes containing unsaturated ligands. Nucleophilic substitution versus nucleophilic attack to ligand: a stereochemistry driven outcome
Author/Authors
Belli Dell’Amico، نويسنده , , Daniela and Broglia، نويسنده , , Claudio and Labella، نويسنده , , Luca and Marchetti، نويسنده , , Fabio and Mendola، نويسنده , , Daniele and Samaritani، نويسنده , , Simona، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
8
From page
181
To page
188
Abstract
The reactivity of mixed complexes [PtCl2(L)(L′)] (L = MeCN, EtCN, CO), L′ = PPh3; L = η2-C2H4, CO; L′ = MeCN, EtCN) towards diethylamine has been investigated. The processes are chemo- (substitution versus addition) and stereo-selective in dependence of the stereochemistry of the precursor. The structures of [SP4-4]-[PtCl(CONEt2)(NHEt2)(PPh3)], [SP4-4]-1, trans-[PtCl2(NHEt2)(PPh3)], trans-2, and cis-[PtCl2{(E-)HNC(NEt2)Me}(PPh3)], cis-3a, are reported.
Keywords
addition reactions , Platinum , Substitution reactions , Unsaturated ligands
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2013
Journal title
INORGANICA CHIMICA ACTA
Record number
1331637
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