Title of article :
Platinum(II) complexes containing unsaturated ligands. Nucleophilic substitution versus nucleophilic attack to ligand: a stereochemistry driven outcome
Author/Authors :
Belli Dell’Amico، نويسنده , , Daniela and Broglia، نويسنده , , Claudio and Labella، نويسنده , , Luca and Marchetti، نويسنده , , Fabio and Mendola، نويسنده , , Daniele and Samaritani، نويسنده , , Simona، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
The reactivity of mixed complexes [PtCl2(L)(L′)] (L = MeCN, EtCN, CO), L′ = PPh3; L = η2-C2H4, CO; L′ = MeCN, EtCN) towards diethylamine has been investigated. The processes are chemo- (substitution versus addition) and stereo-selective in dependence of the stereochemistry of the precursor. The structures of [SP4-4]-[PtCl(CONEt2)(NHEt2)(PPh3)], [SP4-4]-1, trans-[PtCl2(NHEt2)(PPh3)], trans-2, and cis-[PtCl2{(E-)HNC(NEt2)Me}(PPh3)], cis-3a, are reported.
Keywords :
addition reactions , Platinum , Substitution reactions , Unsaturated ligands
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
