• Title of article

    New PTA (1,3,5-triaza 7-phosphaadamantane) derivatives associating zwitterionic structure and coordinative ability

  • Author/Authors

    Bergamini، نويسنده , , Paola and Marvelli، نويسنده , , Lorenza and Marchi، نويسنده , , Andrea and Bertolasi، نويسنده , , Valerio and Fogagnolo، نويسنده , , Marco and Formaglio، نويسنده , , Paolo and Sforza، نويسنده , , Fabio، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2013
  • Pages
    8
  • From page
    11
  • To page
    18
  • Abstract
    The reactions of PTA (1,3,5-triaza 7-phosphaadamantane) and HMTA (1,3,5,7-tetraazaadamantane) with 1,3-propanesultone or 1,4-butanesultone gave the water soluble zwitterionic derivatives PTA+C3H6SO3− (1), PTA+C4H8SO3− (2), HMTA+C3H6SO3− (3) and HMTA+C4H8SO3− (4). The crystal structure of HMTA+C3H6SO3 is reported. The coordinative ability of 1–4 towards Pt(II) and Ru(II) has been investigated and the antiproliferative activity of ligands and complexes has been tested in two human ovarian cancer cell lines, A2780 and SKOV3.
  • Keywords
    PTA , Zwitterionic , Platinum , Antiproliferative activity , N-Alkylation , Ruthenium
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2013
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1331802