Title of article
New compounds constructed from bi-antimony capped Keggin polyoxoanions and different coordination fragments
Author/Authors
Shi، نويسنده , , Shu-Yun and Teng، نويسنده , , Hong-Hui and Chang، نويسنده , , Li-Min and Wang، نويسنده , , Yan and Xiao، نويسنده , , Li-Na and Cui، نويسنده , , Xiao-Bing and Xu، نويسنده , , Ji-Qing، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
172
To page
176
Abstract
Two new compounds [Cu(enMe)2][Cu(enMe)2(H2O)][SiMoV6MoVI6Sb2O40] (1) and [Ni(en)2]2[SiMoV6MoVI6Sb2O40] (2) (enMe = 1,2-diaminopropane, en = 1,2-ethylenediamine) have been hydrothermally synthesized and characterized by IR, UV–Vis spectroscopy, X-ray photoelectron spectroscopy (XPS), powder XRD analyses, elemental analyses and single crystal X-ray diffraction. The two compounds represent the first examples of hybrids based on bi-antimony capped Keggin polyanions {SiMo12Sb2O40} and different transition metal coordination complexes.
Keywords
Polyoxometalate , hydrothermal synthesis , structure , Bi-antimony capped Keggin polyoxometalates
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2013
Journal title
INORGANICA CHIMICA ACTA
Record number
1331846
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