Title of article
A new vanadium(IV)-bridged polyoxotungstate containing mixed valence-antimony(III,V)
Author/Authors
Wang، نويسنده , , Bin and Xu، نويسنده , , Ling-Xiao and Meng، نويسنده , , Rui-Qi and Suo، نويسنده , , Lin and Li، نويسنده , , Bao and Wu، نويسنده , , Li-Xin and Bi، نويسنده , , Li-Hua، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
274
To page
278
Abstract
A new mixed-valence SbV/III containing vanadium-substituted polyoxotungstate Na10[{SbV(OH)3}2{VIVO(H2O)}2{SbIIIW9O33}2]·32H2O (1-Na) has been synthesized by routine synthetic reaction and characterized by IR, XPS, elemental analysis. The polyoxoanion [{SbV(OH)3}2{VIVO(H2O)}2{SbIIIW9O33}2]10− (1) consists of two trilacunary species β-B-SbIIIW9O33 connected by two VIVO(H2O) groups and two SbV(OH)3 units. The cyclic voltammetry and catalytic activity of 1-Na for the oxidation of n-hexadecane under green condition have been measured.
Keywords
vanadium , Polyoxotungstate , Mixed-valance cluster , crystal structure , Antimony
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2013
Journal title
INORGANICA CHIMICA ACTA
Record number
1332039
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