Title of article
A manganese sulfite with extended metal–oxygen–metal bonds exhibiting hydrogen uptake
Author/Authors
K. Prabhakara Rao، نويسنده , , A. Govindaraj، نويسنده , , C.N.R. Rao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
3571
To page
3575
Abstract
A manganese sulfite of the formula Mn5(OH)4(SO3)3·2H2O, I{a=7.5759(7) Å, b=8.4749(8) Å, c=10.852(1) Å, β=100.732(2)°, Z=2, space group=P21/m (no. 11), R1=0.0399 and wR2=0.1121 [for R indexes I>2σ(I)]}, comprising Mn3O14 units and extended Mn–O–Mn bonds along the three dimensions has been synthesized under hydrothermal conditions. It has narrow channels along the b-axis and exhibits hydrogen storage of 2.1 wt% at 300 K and 134 bar.
Keywords
Manganese sulfite , Hydrothermal synthesis , X-ray diffraction , Metal–oxygen–metal bonds , Antiferromagnetism , Hydrogen storage
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year
2007
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Record number
1332951
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