Title of article
Crystallographic and infrared spectroscopic study of bond distances in Ln[Fe(CN)6]·4H2O (Ln=lanthanide)
Author/Authors
Xianju Zhou، نويسنده , , Wing-Tak Wong، نويسنده , , Michèle D. Faucher، نويسنده , , Peter A. Tanner، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
8
From page
3057
To page
3064
Abstract
Along with crystallographic data of Ln[Fe(CN)6]·4H2O (Ln=lanthanide), the infrared spectra are reassigned to examine bond length trends across the series of Ln. The changes in mean Ln–O, Ln–N, Ctriple bond; length of mdashN and Fe–C distances are discussed and the bond natures of Ln–N and Ln–O are studied by bond length linear or quadratic fitting and comparisons with relevant ionic radii. The two different Ctriple bond; length of mdashN bond distances have been simulated by the covalo-electrostatic model.
Keywords
Bond distance , Lanthanide contraction , Infrared spectra , crystal structure , Covalo-electrostatic model
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Serial Year
2008
Journal title
JOURNAL OF SOLID STATE CHEMISTRY
Record number
1333517
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