Author/Authors :
Liushan Luo، نويسنده , , Xiaoyuan Huang، نويسنده , , Ning Wang، نويسنده , , Hongyan Wu، نويسنده , , Wenbin Chen، نويسنده , , Zihao Feng، نويسنده , , Huiping Zhu، نويسنده , , Xiaoling Peng، نويسنده , , Yongxian Li، نويسنده , , Ling Huang، نويسنده , , Shantang YUE، نويسنده , , Yingliang Liu، نويسنده ,
Abstract :
Two new lanthanide coordination polymers H2N(CH3)2·[EuIII2(L1)3(L2)] (1, L1=isophthalic acid dianion, L2=formic acid anion) and [LaIII(2,5-PDC)(L2)](2, 2,5-PDC=2,5-pyridinedicarboxylate dianion) were synthesized under solvothermal conditions. It is of interest that the formic ligand (L2) is not contained in the stating materials, but arises from the water molecule-enhanced CO2 insertion during the solvothermal process. Both of the two compounds exhibit complicated three dimensional sandwich-like frameworks.
Keywords :
lanthanide complex , CO2 insertion , Luminescence , Hydrothermal synthesis
