Formation of nano-size oxide particles and δ-ferrite at elevated temperature in 9Cr-ODS steel

Excellent high-temperature strength and resistance to radiation damage of 9Cr Oxide Dispersion Strengthened (9Cr-ODS) martensitic steel have been realized by nano-size Y–Ti–O complex oxide particles dispersed in the matrix and a dual phase structure consisting of α′-martensite and δ-ferrite. These are produced by mechanically alloying Fe–Cr–Ti powders with Y2O3 followed by a hot-consolidation process. Therefore, the hot-consolidation process is the issue to be clarified for the formation of nano-size oxide particle and δ-ferrite. The temperature dependence of the formation and development of nano-size oxide particles and δ-ferrite using mechanically alloyed 9Cr-ODS raw powder were investigated applying X-ray Diffraction and Small Angle X-ray Scattering measurement at SPring-8 and by Electron Probe Micro Analysis. In situ heating measurement techniques with XRD and SAXS enabled real-time observation of phase transformations and allowed correlation between formation of nano-size oxide particle and δ-ferrite.