The effect of different environments on Nafion degradation: Quantum mechanics study

Degradation of the Nafion electrolyte in Proton Exchange Membrane Fuel Cells (PEMFCs) limits the lifetime, motivating development of materials that resist degradation. The mechanism for degradation of Nafion under fuel cell conditions remains uncertain. Studies of Nafion degradation in concentrated OHradical dot environments, such as Fenton or vapor HOOH tests, show that the main chain significantly degrades in these conditions. However it has not been established whether this applies to fuel cell conditions. We have used quantum mechanics (Density Functional Theory with the B3LYP and M06 functionals) to determine the mechanism of Nafion degradation under both concentrated OHradical dot and fuel cell conditions. These studies confirm that under concentrated OHradical dot conditions Nafion degrades when peroxide radicals attack end groups (–COOH, –CFCF2, –CF2H); followed by degradation of Nafion along the polymer main chain, as proposed previously. However we find that under fuel cell conditions, Nafion degradation occurs along the polymer side chain starting with Hradical dot attacking the side chain groups such as the sulfonic acid, –SO3−. We find that it is easier for OHradical dot to attack the main chain than Hradical dot, while vice versa, it is easier for Hradical dot radical to attack the side chain than OHradical dot.