Author/Authors :
Azizian، Javad نويسنده Department of chemistry, Science and Reaserch branch, Islamic azad university, Tehran, Iran Azizian, Javad , Entezari، Mahdieh نويسنده Department of chemistry, , Mahshahr branch, Islamic azad university, Mahshahr, Iran Entezari, Mahdieh , Anaraki Ardakani، Hossein نويسنده Department of chemistry, , Mahshahr branch, Islamic azad university, Mahshahr, Iran Anaraki Ardakani, Hossein , Zomorodbakhsh، Shahab نويسنده Department of chemistry, , Mahshahr branch, Islamic azad university, Mahshahr, Iran Zomorodbakhsh, Shahab
Abstract :
Ab initio HF/6-31G* Methode was employed to calculate the bond length in 2- phosphinanes when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2-boromo substituented phosphinanes. The effect of anomeric effect have been effected on the bond length in
2- phosphinanes.
