Author/Authors :
Dinh، نويسنده , , L.N. and Schildbach، نويسنده , , M.A. and Herberg، نويسنده , , J.L. and Saab، نويسنده , , A.P. and Weigle، نويسنده , , J.C. and Chinn، نويسنده , , S.C. and Maxwell، نويسنده , , R.S. and McLean II، نويسنده , , W.، نويسنده ,
Abstract :
The physical and chemical properties of 1,4-diphenylbutadiyne (DPB) blended with carbon-supported Pd (DPB–Pd/C) in the form of pellets during hydrogenation were investigated. A thermogravimetric analyzer (TGA) was employed to measure the kinetics of the hydrogen uptake by the DPB getter pellets. The kinetics obtained were then used to develop a semi-empirical model, based on gas diffusion into solids, to predict the performance of the getter pellets under various conditions. The accuracy of the prediction model was established by comparing the prediction models with independent experimental data on hydrogen pressure buildup in sealed systems containing DPB getter pellets and subjected to known rates of hydrogen input. The volatility of the hydrogenated DPB products and its effects on the hydrogen uptake kinetics were also analyzed.
