Dielectric relaxation in ferroelectric PZT–PVDF nanocomposites

Composites of electroactive ceramics and ferroelectric polymers are important for applications since they combine the most important features of the both phases and their properties can be easily tailored to various requirements. As the dielectric permittivity is involved in figures of merit of the quantities important for applications we studied dielectric response of Pb(Zr0.5Ti0.5)O3–polyvinylidene fluoride nanocomposites over a wide frequency and temperature range. It was found that though the permittivity value of the composites is high due to the high permittivity of the ceramics, the glass transition of the polymer and dielectric relaxation related to the wide-angle oscillation of polar groups attached to the main polymer chain determine the dielectric behaviour of the composites.