Title of article :
Mِssbauer and IR investigations of iron ultraphosphate glasses
Author/Authors :
Karabulut، نويسنده , , M. and Metwalli، نويسنده , , Norah E. Mulvaney-Day، نويسنده , , D.E. and Brow، نويسنده , , R.K.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The structures of xFeO · (1−x)P2O5 glasses (0⩽x⩽0.50) prepared in sealed silica ampoules have been investigated using Mössbauer and infrared (IR) spectroscopies. Mössbauer results indicate that the glasses contain 6–18% Fe(III). Both Fe(II) and Fe(III) ions occupy octahedral coordination environments in these glasses. Analysis of the IR spectra indicates that the structure of glass transforms systematically from a three-dimensional P2O5 network (dominated by Q3 tetrahedra) to a two-dimensional network (dominated by Q2 units) as the FeO content increases. This transformation is evidenced by the replacement of the IR band at 1380 cm−1 attributed to PO vibrations on isolated Q3 sites with the band at 1260 cm−1 band which is attributed to asymmetric vibrations of PO2 groups on the Q2 tetrahedra. In addition, a new IR band at 1317 cm−1 is created when FeO is added to P2O5 and this band is assigned to PO bonds that participate in the coordination environments of the Fe-octahedra. At x∼0.35 FeO, the PO bonds that remain are only those that coordinate with the Fe-octahedra. These structural changes are similar to those observed for other ultraphosphate glasses.
Journal title :
Journal of Non-Crystalline Solids
Journal title :
Journal of Non-Crystalline Solids