Title of article
Hydrosilylation of allyl derivatives with T, D and M type hydrosilanes
Author/Authors
Masayasu Igarashi، نويسنده , , Tomohiro Matsumoto، نويسنده , , Toshiaki Kobayashi، نويسنده , , Kazuhiko Sato، نويسنده , , Wataru Ando، نويسنده , , Shigeru Shimada، نويسنده , , Masanao Hara، نويسنده , , Hiroshi Uchida، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
7
From page
421
To page
427
Abstract
Hydrosilylation reactions of allyl derivatives (i.e., allyl acetate, N,N-dimethylallylamine and allyl ethyl ether) with hydrosilanes (i.e., octahydridosilsesquioxane, 2,4,6,8-tetramethylcyclotetrasiloxane, and tetramethyldisiloxane) were carried out in the presence of the Karstedtʹs catalyst in order to compare their structure–reactivity relationship. The effects of a phosphine ligand on the conversion and the selectivity were also investigated with PPh3 as an additive to the Karstedtʹs catalyst.
Keywords
Hydrosilylation , Catalysis , Octahydridosilsesquioxane , Allyl derivatives
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1369598
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