• Title of article

    Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins

  • Author/Authors

    Hailin Dong، نويسنده , , Yanfeng Jiang، نويسنده , , Heinz Berke، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2014
  • Pages
    6
  • From page
    17
  • To page
    22
  • Abstract
    The rhenium (I) complex [Re(CH3CN)3Br2(NO)] catalyzes the homogeneous hydrosilylation of a variety of substituted acrylonitriles, which were converted into the corresponding silyl-substituted alkanes with high regioselectivity of up to 94%. The products were analyzed by 1H NMR and GC–MS. A rhenium specific mechanism is proposed for the hydrosilylation of olefins.
  • Keywords
    Rhenium , Acrylonitrile , alkene , Homogeneous catalysis , dehydrogenative silylation , Hydrosilylation
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2014
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1369610

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1369610