Title of article :
Cyanide bridged trinuclear complexes with FeCNMCl2NCFe backbones (M=Ni, Cu, Zn)
Author/Authors :
Guy N. Richardson، نويسنده , , Heinrich Vahrenkamp، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2000
Abstract :
The title complexes were prepared from Cp(dppe)FeCN and the metal chlorides. Cp(dppe)FeCNCuCl and Cp(dppe)FeCNCuCl2NCFe(dppe)Cp were characterised by structural determination. Electrochemical measurements have shown that there is no electronic interaction between the two outer iron centres in the NiCl2 and CuCl2 derived complexes. The ZnCl2 derived complex, however, shows two separate redox waves that allows us to assign the mono-oxidised species as a class II mixed valent species according to the classification of Robin and Day.
Keywords :
structure , Trinuclear complexes , Cyanide bridging , Metal?metal interactions , Electrochemistry
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry