• Title of article

    Regioselective CF and CH bond activation: synthesis and structure of an asymmetric rhodium complex comprising a η5:η1:η1-cyclopentadienyl-bis(phosphine) ligand

  • Author/Authors

    Mark Nieuwenhuyzen، نويسنده , , Graham C. Saunders، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    4
  • From page
    292
  • To page
    295
  • Abstract
    The reaction between [(η5-C5Me4H)RhBr(μ-Br)]2 and (C6F5)2PCH2CH2P(C6F5)2 proceeds in refluxing benzene via the cleavage of two CF and CH bonds and the formation of two CC bonds to give the unexpected asymmetric compound [{η5-C5HMe2-3,4-[CH2C6F4P(C6F5)CH2]2-1,2}RhBr]Br with high selectivity. The formulation has been confirmed by single-crystal X-ray diffraction.
  • Keywords
    Rhodium , Carbon?fluorine bond activation , Carbon?hydrogen bond activation
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1369782

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1369782