Title of article
The preparation, molecular structure and catalytic relevance of Ti(OSiPh3)4 and Ti(OGePh3)4
Author/Authors
Brian F.G. Johnson، نويسنده , , Marek C. Klunduk، نويسنده , , Caroline M. Martin، نويسنده , , Andrew M. Beale and Gopinathan Sankar، نويسنده , , Simon J. Teate، نويسنده , , John Meurig Thomas، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
5
From page
221
To page
225
Abstract
The preparation, spectroscopic characterisation and molecular structures of the four-coordinate, tetrahedral and monomeric compounds Ti(OSiPh3)4 and Ti(OGePh3)4 are presented and discussed. The catalytic inactivity of both of these compounds may be rationalised on the basis of the steric inaccessibility of the substrates to the Ti(IV) active sites, which are effectively shrouded by the bulky triphenyl groups.
Keywords
Micro-crystal diffraction , Epoxidation reaction , Catalyst
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1369818
Link To Document