Title of article
New ionic fluorenylnickel complexes: Synthesis and solid state structure
Author/Authors
Andrzej Kozio?، نويسنده , , Lucjan B. Jerzykiewicz، نويسنده , , Iwona Justyniak، نويسنده , , Tadeusz Lis، نويسنده , , Stanis?aw Pasynkiewicz، نويسنده , , Antoni Pietrzykowski، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
5
From page
22
To page
26
Abstract
New fluorenylnickel complexes [M(THF)n]+[Ni(η5-Flu)(η1-Flu)2]− (M = +48 Li, 1 and M = Na, 2) have been obtained in the reaction of nickel bromide with fluorenyllithium and -sodium. The X-ray molecular structures of 1 (monoclinic; P21/c) and 2 (orthorhombic; Fdd2) reveal that in both complexes two fluorenyl ligands are bonded to the nickel atom by η1 bond and the third one is bonded to the nickel atom by η5 bond. Complexes 1 and 2 are the first structurally characterized nickel complexes bearing fluorenyl ligands.
Keywords
nickel , Crystal structure determination , Fluorene
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1370604
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