• Title of article

    Asymmetric synthesis of fluorinated β-hydroxy esters via ruthenium-mediated hydrogenation

  • Author/Authors

    Paul D. Blanc، نويسنده , , V. Ratovelomanana-Vidal، نويسنده , , J.-P. Gillet، نويسنده , , J.-P. Genêt، نويسنده ,

  • Issue Information
    دوفصلنامه با شماره پیاپی سال 2000
  • Pages
    3
  • From page
    128
  • To page
    130
  • Abstract
    The homogeneous asymmetric hydrogenation reactions of fluorinated β-keto esters using ruthenium(II) complexes bearing atropoisomeric diphosphines such as BINAP and MeOBIPHEP have yielded the corresponding β-hydroxy esters in quantitative yield with ee that ranged between 42 and >95%.
  • Keywords
    Ruthenium catalysts , Chiral hydrogenation , Fluoroorganic compounds
  • Journal title
    Journal of Organometallic Chemistry
  • Serial Year
    2000
  • Journal title
    Journal of Organometallic Chemistry
  • Record number

    1370742