Title of article
Asymmetric synthesis of fluorinated β-hydroxy esters via ruthenium-mediated hydrogenation
Author/Authors
Paul D. Blanc، نويسنده , , V. Ratovelomanana-Vidal، نويسنده , , J.-P. Gillet، نويسنده , , J.-P. Genêt، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
3
From page
128
To page
130
Abstract
The homogeneous asymmetric hydrogenation reactions of fluorinated β-keto esters using ruthenium(II) complexes bearing atropoisomeric diphosphines such as BINAP and MeOBIPHEP have yielded the corresponding β-hydroxy esters in quantitative yield with ee that ranged between 42 and >95%.
Keywords
Ruthenium catalysts , Chiral hydrogenation , Fluoroorganic compounds
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1370742
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