Title of article
Mechanistic study of the hydroformylation of styrene catalyzed by the rhodium/BDPP system
Author/Authors
Inmaculada del R??o، نويسنده , , Oscar Pàmies، نويسنده , , Piet W.N.M. van Leeuwen، نويسنده , , Carmen Claver، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2000
Pages
7
From page
115
To page
121
Abstract
The hydroformylation of styrene using the rhodium [Rh(μ-OMe)(COD)]2/BDPP [(2S,4S)-bis(diphenylphosphine)pentane] system was studied. Since in situ infrared spectroscopic experiment studies showed a considerable number of absorptions at low pressure, an HPNMR exploration was carried out and a kinetic study was performed in the pressure range between 8 and 30 bar. These studies revealed the presence of different species as resting states depending on the CO/H2 total pressure.
Keywords
HPNMR , HPIR , hydroformylation , Rhodium complexes , kinetics , Styrene
Journal title
Journal of Organometallic Chemistry
Serial Year
2000
Journal title
Journal of Organometallic Chemistry
Record number
1370969
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